Bark with a bite

Eucalyptus helps remove chromium

 
By T V Jayan
Published: Monday 31 October 2005

Adsorbs toxic chromium indian scientists have found the bark of widely grown eucalyptus can help solve one of the most gruelling industrial problems: removing chromium from effluents. The bark not only reduces chromium content in industrial waste to safe levels, but also enables the toxic metal's recovery for reutilisation, claim researchers at the Indian Institute of Technology (iit), Delhi.

Chromium can cause lung cancer and damage to other vital organs like the kidney, liver and stomach. It is also toxic to other life forms including plants and microorganisms. The metal occurs in two forms -- Cr (vi) and Cr (iii), the former being 500 times more toxic than the latter. The maximum levels of chromium oxides permitted in wastewater are 5 parts per billion (ppb) for Cr (iii) and 0.05 ppb for Cr (vi).

Used in several industrial processes, chromium is normally removed from effluents through precipitation but that does not bring its levels to acceptable limits. Besides, its safe disposal or recovery from the slurry is considered tough.

In India, the leather industry is the biggest user of chromium. The element is used as a cheap tanning agent. The tanning process takes up only 60-80 per cent of the applied chromium and the rest is discharged. Though chromium in effluents from tanneries is usually in the form of Cr (iii), organic compounds present in the industrial waste convert Cr (iii) into the more toxic Cr (vi).

Kamal Pant of iit and his research student Vikrant Sarin used two samples of industrial waste from an automobile plant near Delhi, where nickel-chromium spraying was being done. They contained 250 ppm (parts per million) and 500 ppm of chromium. As the adsorption process involving eucalyptus bark is effective at levels less than 200 ppm, the scientists first introduced a membrane filtration process. When the effluent was passed over a bed of eucalyptus bark, the scientists found up to 99 per cent of chromium was removed from the waste water. The process was repeated to bring chromium concentration down to its safe limit. The findings will appear in a forthcoming issue of Bioresource Technology .

The scientists also tried out several other cheaply available materials such as coconut husk fibres, sugarcane bagasse, sugar beet pulp, and saw dust, but found the eucalyptus bark the most efficient.

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