Two technologies that shape our future
A tremor ran through the cutting- edge electric car industry last month. Mathieu Tenenbaum, working with French automaker Renault, was just another faceless name till then. But one espionage story that hit the newsstands made him infamous in a single stroke.
Tenenbaum was sacked for spying. Not that he had leaked a closely guarded nuclear secret. It was a mere battery that unleashed high drama in the fiercely competitive world of electric cars.
According to newspaper reports, the French intelligence agencies pointed towards China charging it with stealing the battery technology. Beijing was quick to deny it. Renault did not reveal what had been leaked, but did say it was a huge relief for the company that technical details of its battery technology were safe. Renault and its Japanese affiliate Nissan are spending a whopping US $5 billion to develop electric vehicles that run on batteries.
Not surprising then that the auto major had panicked fearing that the company’s crucial and secret details, vital for its growth, had been let out.
Renault-Nissan has staked its future on the success of battery and its ability to power a vehicle. The joint venture’s CEO Carlos Ghosn has claimed that by 2020, zero-emission, battery-powered vehicles will comprise 10 per cent of the global car market.
The espionage story has laid bare the fact that battery technology in the electric car industry has the potential to pay huge dividends.
Just a month before the story broke, Nissan launched its electric car Leaf. Powered by a 24-kilowatt per hour battery pack, it claims to run about 160 km after being charged once with a top speed of about 145 km per hour.
Leaf has been voted the 2011 European Car of the Year, an award established in 1964 by a collective of automobile magazines.
In the United States, after accounting for subsidy, it costs around $25,000. But this is expensive compared to petrol vehicles. That is why even a small breakthrough in the technology will hugely benefit the industry.
The global battery market, valued at US $100 billion, is projected to grow at 4.8 per cent by 2014, according to Freedonia Group, a publisher of market research reports.
Whats and hows
Batteries today don’t just power vehicles, but dictate how we communicate, read, listen to music, commute, back up our data, adopt green technologies and overcome power cuts.
A battery comprises two electric conductors (electrodes) connected by an electrolyte, the medium for transfer of ions. This produces a flow of current converting chemical energy to electrical power. There are three most common families of batteries—lead-acid, lithium and nickel. Lead-acid is the oldest rechargeable battery and promises to remain in the market for years to come. Its cell contains electrodes of elemental lead and lead oxide in an electrolyte of dissolved sulphuric acid. This battery is heavy because lead has low electrochemical potential. It is, therefore, used mostly in bulky or stationary devices.
At the forefront of battery revolution is lithium-ion 18650, which makes possible a casing of just 18 mm diameter and 65 mm length. Being the lightest metal and the least dense solid element, lithium makes the battery pack portable. It is used in cell phones and laptops. Many companies are now trying it out in electric cars.
Nickel metal hydride has been used in electric cars such as Toyota Prius, but it is double the weight of a lithium battery. Nickel cadmium, once used to power cell phones and laptops, has been replaced by lithium-ion after concern was raised over cadmium’s toxicity.
Lead-acid market in India is valued at Rs 20,000 crore and is growing at 15 to 20 per cent per year. This is the strongest sales growth of any national market. Invented by French physicist Gaston Plante in 1859 (see ‘History of the battery’), the lead-acid battery is here to stay. “It will continue to dominate for the next 20 years,” said L Pugazenthy, executive director of the India Lead Zinc Development Association.
Used in heavy duty vehicles such as cars, tractors and forklifts, it is now common in households. Power cuts have made inverters and battery backup a lucrative industry. It continues to provide power to critical operations like air-traffic control towers, hospitals, rail- road crossings, military installations, submarines and weapons systems. Telephone connectivity, too, is uninterrupted because telecom companies use lead-acid battery as back-up.
“It would be very difficult to replace lead-acid as it has one basic advantage— low cost. The process of refine, reuse and recycle is also fairly simple,” said A Chakrabarty, battery expert and former technical head of Exide, India’s largest battery maker.
|| Companies are competing to develop safe battery packs that can run devices longer
Growth of the renewable energy sector also depends on this chemistry. But the sun does not shine at all times, neither does the wind blow enough. Therefore, battery for this sector must provide power for at least five days, or 120 hours. For this, thicker electrodes are used since they get eaten away during charge cycles.
“From a cost-performance standpoint, the lead-acid battery is a good choice for storage of renewable energy,” said Jerome Cole of International Lead Zinc Research Organisation, a nonprofit in the US.
Nickel metal hydride battery packs could cost four times more than leadacid, said P C Pant, scientist in-charge of battery projects at the Ministry of New and Renewable Energy (MNRE).
In remote areas, off-grid projects require user-friendly and established technologies. Projects that directly feed the grid do not need batteries. Before 2010, India’s demand for lead-acid batteries with off-grid solar projects was about 0.3 million a year.
The demand increased after the Jawaharlal Nehru National Solar Mission was mandated to generate 2,000 MW off-grid electricity by 2022. In the first phase, which ends in 2013, there must be 200 MW of off-grid generation. This will increase the annual demand to more than 1.5 million battery packs, Pant said. Big players like Andhra Pradesh-based Aamara Raja, who were not active in this sector, are making an aggressive entry. All off-grid photovoltaic projects need inverters to convert direct current into alternate current. Companies like Microtek and Su-kam that manufacture inverters have, therefore, diversified into providing batteries for solar applications.
However, lead-acid battery has the drawback of being bulky and heavy. This is the reason companies are experimenting with lithium-ion.
Producing maximum power with minimum battery weight is the industry’s main challenge. Cracking this code will prove to be a huge breakthrough that will help replace or minimise use of petrol and diesel devices with a batterypowered alternative.
The unit, kilowatt per kilogramme (KW/KG), is the most important parameter in the battery world. Also called gravimetric energy density, this unit is used to compare different battery packs (see ‘Units that drive technology’).
Companies are now competing to develop safe battery packs that can run devices longer on one charge over thousands of charge-discharge cycles. Japanese major Sony was the first to commercialise lithium-ion battery, much lighter than lead-acid. It used carbon material on the anode.
Today, graphite is a popular choice for anode. The way ahead for lithiumion battery lies in experimenting further with different electrodes. Just about five years ago, cell phones or laptops powered by lithium doubled as bombs. There were instances of gizmos being blown into pieces. Companies recalled their batteries, which cost them millions of rupees. Now, there are control systems for monitoring and protective circuiting. Technology has definitely evolved, but will it crack the crucial code?
If battery is the future of energy storage, the most efficient pack is lithium-based as it has the best electro- chemical potential
. Just one lithium-ion battery can efficiently run a hi-tech cellular phone.
It has replaced the nickel-based cell phone that is bulkier and requires frequent charging.
Nickel battery also suffers from memory loss. When charged repeatedly after partial discharge, it forgets its usage capacity. A lithium battery does not suffer from amnesia.
Market research has predicted that demand for lithium will be spurred by the popularity of portable electronic devices like cell phones, gaming systems and laptops.
Because of its high energy density, it is the leading choice of battery for electric vehicle manufacturers.
India got its first battery car, Reva, in 2001. Powered by lead-acid, it has its drawbacks. The car has limited driving range because of its weight. Its battery takes long to recharge. The company is now experimenting on 100 cars powered by lithium-ion. They may be in the market soon.
Lithium-ion chemistry has emerged as a leading solution to electric vehicle batteries. Its performance is seen best in roadster Tesla
(see ‘Tesla’s lithium leap
On kilowatt basis, lithium-ion batteries cost three to five times those of competing chemistries. “The high cost derives from the raw material, cell packaging and need for special manufacturing facilities,” said R V Alagesan, scientist at the Central Electrochemical Research institute in Tamil Nadu.
Lithium is also known to be inherently unstable, especially while charging.
It has the potential of thermal runaway— temperature quickly rises to the melting point of metallic lithium and causes exothermic reaction.
To solve this, research was conducted in the US in 1980s, substituting metallic lithium with electrodes containing lithium-ion.
Scarce and valuable
If lithium is the future oil, South America may soon become the next West Asia.
The continent dominates lithium production, with Chile and Argentina accounting for 10,000 tonnes of the global production of 21,400 tonnes (see ‘Lithium storehouse’).
With an estimated 5.4 million tonnes, Bolivia is sitting on half of the lithium reserves and an even higher percentage of salt reserves, a source considered ideal for batteries. Salar de Uyuni, the world’s largest salt flat in Bolivia, has attracted car manufacturers and lithium miners. But unlike Argentina and Chile, the Bolivians are playing hard to get.
The country’s mines minister Luiz Alberto Echazu has said companies wanting to work on the salt pan must develop industries there. Bolivian president Evo Morales also made it clear that his country will not export raw material forever. He wants the manufacturing base of lithium-ion battery and electric car to shift to Bolivia.
Global demand for lithium will not increase until millions of electric vehicles are produced each year
. It is understood that 400 gramme of lithium is required to produce a battery pack with one KWH output. To exhaust the 2010 projection of 9.9 million tonne reserves, 25 billion KWH battery packs could today power more than a billion electric cars, each with a 24 KWH battery pack similar to that of Nissan Leaf.
Bolivia is clearly the destination of the future.
A growing industry
Battery technology has been making rapid strides. Even the good old leadacid chemistry has improved drastically. Some three decades ago, lead-acid packs were available mostly in hard rubber containers and required frequent addition of distilled water. “Now they come in poly propylene containers and are almost maintenance-free,” said V K Aggarwal, chairperson of Supreme Batteries. Life of a battery has also increased from 12 to 18 months, to 36 to 42 months, and its capacity is twice per unit of lead used.
In its effort to bring out thin batteries, Apple introduced lithium-ion polymer in its new generation portable devices. Polymer, along with a thin layer of gel, works as an electrolyte making the battery an unbelievable one millimetre thin. It comes packed in a pouch replacing the traditional metallic cylinder hard shell with heat-sealable foils.
Scientists at Stanford University
are working to enhance the lithium-ion technology. The research seeks to improve the anode’s capacity by replacing carbon with silicon. This can hold 10 times more lithium.
Another option, still being explored, is the supercapacitor. It can store electric energy when disconnected from the charging circuit and can be charged over and over again.
But instead of working as a replacement for battery, it is used to enhance one another.
It is true that research on battery chemistry will take long to transfer into actual application. But it is equally true that the dream of an energy-secure and environment-friendly future can be realised only through the battery.